Kr. Wirth et al., THE CHENGWATANA VOLCANICS, WISCONSIN AND MINNESOTA - PETROGENESIS OF THE SOUTHERNMOST VOLCANIC-ROCKS EXPOSED IN THE MIDCONTINENT RIFT, Canadian journal of earth sciences, 34(4), 1997, pp. 536-548
The southernmost exposed rocks of the North American Midcontinent rift
system (1100 Ma) consist of 3000 m of mafic volcanic flows and minor
interflow sediment exposed along the St. Croix River in Minnesota and
Wisconsin. The flows are mostly high-Fe tholeiitic basalt with plagioc
lase phenocrysts and ophitic to subophitic clinopyroxene. Abundant sec
ondary chlorite, epidote, and actinolite indicate the group was metamo
rphosed to greenschist facies (similar to 350 degrees C). Low sodium (
M4 site) and tetrahedral aluminum (Al-IV) contents of actinolite indic
ate low-pressure metamorphism (0.25 GPa) and imply a geothermal gradie
nt of 45-50 degrees C/km. Low magnesium (Mg# = 0.37-0.58) and Ni conte
nts (36-185 ppm) indicate the basalts have undergone significant fract
ionation and are not primary mantle melts. Incompatible element abunda
nces are inversely correlated with Mg#, and most samples plot within e
ither high or low trace element groups (e.g., Ti, P, Zr). The basalts
are enriched in the light rare earth elements and Th, and are variably
depleted in Ta and Nb relative to La and Th. Initial Nd-143/Nd-144 co
mpositions of the group range from 0.51099 to 0.51122 (initial epsilon
(Nd) = -4.5 to +0.1). Most flows have isotopic compositions within a r
elatively limited range (initial epsilon(Nd) = -2.5 to -1.6), but exhi
bit variable trace element abundances. Flows with the highest and lowe
st initial Nd-143/Nd-144 ratios have isotopic compositions that are in
versely correlated with trace element abundances and ratios (e.g., La/
Yb, Th/La, Th/Ta). The combined geochemical data suggest that the Chen
gwatana basalts originated from plume-derived melts and underwent vari
able fractional crystallization and crustal contamination. These melts
may have interacted with lithospheric mantle enriched during Penokean
subduction.