Ng. Rizvanova et al., Zircon reaction and stability of the U-Pb isotope system during interaction with carbonate fluid: experimental hydrothermal study, CONTR MIN P, 139(1), 2000, pp. 101-114
The interpretation of metamorphically induced U-Pb isotopic discordance req
uires a thorough understanding of zircon-fluid interactions. With this aim
we have studied the behaviour of metamict and crystalline zircon phases and
their U-Pb systems by cathodoluminescence after treatment by 2M Na2CO3 sol
ution at T = 200-800 degrees C and P = 1-5 kbar for 3-14 days, X-ray diffra
ction, microprobe and isotope dilution analysis. The data indicate that zir
con transformation under hydrothermal conditions depends on the experimenta
l conditions and the degree of structural damage. Reconstitution of defecti
ve and impurity-enriched zones of metamict zircon (homogenization of impure
element concentrations and increase of crystallinity) was observed at 400
degrees C and P = 1 kbar. Considerable lead and uranium loss occurred under
these conditions. As a result of zircon dissolution, newly formed baddeley
ite accommodating U from 2M Na2CO3 solution and Zr-Na-silicate were recogni
zed. This process intensified with increasing pressure. Study of crystallin
e zircon indicates that migration of U and Pb took place only during dissol
ution of zircon at T above 650 degrees C. In the presence of carbonate-ions
essential U and Pb amounts are lost from metamict zircon at a lower P-T th
an is typical for greenschist facies metamorphism.