An extraction process has been studied on a laboratory scale for the pretre
atment of municipal solid waste (MSW) incinerator fly ash to remobilize Cr,
Cu, Ph, and Zn. Five different types of fly ashes were treated with HCl, n
itrilotriacetic acid (NTA), ethylendiaminetetraacetate (EDTA), or diethylen
etriaminepentaacetate (DTPA) in a batch process in the pH range 2.5-10. The
extraction of heavy metals by HCl was dependent on pH, increasing with inc
reasing acid concentration. The efficiency of the chelating agents was inde
pendent of pH. By the treatment with 3.0% EDTA or DTPA, 20-50% of Cr, 60-95
% of Cu, 60-100% of Ph, and 50-100% of Zn were extracted in the pH range 3-
9. NTA was also effective in extracting Cr, Cu, and Zn. The maximum extract
ion of Cr, Cu, Ph, and Zn was obtained at 0.3-1.0% concentration of the che
lating agents. NTA was effective in extracting Pb at a concentration as low
as 0.1%. Extraction behavior of other elements during the treatment was al
so studied. The leaching test on the residues after the treatment with chel
ating agents showed that the fly ashes were successfully detoxified to meet
the guideline for landfilling. (C) 2000 Elsevier Science B.V. All rights r
eserved.