CONVERSION OF CARBONIMIDODITHIOATES TO CARBAMATES

Authors
ANBAZHAGAN M REDDY TI RAJAPPA S
Citation
M. Anbazhagan et al., CONVERSION OF CARBONIMIDODITHIOATES TO CARBAMATES, Journal of the Chemical Society. Perkin transactions. I, (11), 1997, pp. 1623-1627
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
11
Year of publication
1997
Pages
1623 - 1627
Database
ISI
SICI code
0300-922X(1997):11<1623:COCTC>2.0.ZU;2-#
Abstract
Carbonimidodithioates derived from primary amines or alpha-amino acid esters have been converted to N-benzyloxycarbonyl derivatives under mi ld conditions by treatment first with sodium benzyl alcoholate and the n with water, N-Benzyloxycarbonyl alpha-amino acids have been generate d from the methyl esters by alkaline hydrolysis or from the allyl este rs by Pd-0-catalysed de-allylation.