Study of low-frequency polarized spectra of a mixed para-dibromobenzene-para-bromochlorobenzene crystal

Citation
Vf. Shabanov et Ma. Korshunov, Study of low-frequency polarized spectra of a mixed para-dibromobenzene-para-bromochlorobenzene crystal, OPT SPECTRO, 88(4), 2000, pp. 527-528
Citations number
7
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
OPTICS AND SPECTROSCOPY
ISSN journal
0030400X → ACNP
Volume
88
Issue
4
Year of publication
2000
Pages
527 - 528
Database
ISI
SICI code
0030-400X(200004)88:4<527:SOLPSO>2.0.ZU;2-N
Abstract
Polarization studies of low-frequency Raman spectra of a mixed (1 : 1) para -dibromobenzene-para-bromochlorobenzene crystal are performed. The spectrum of the mixed crystal is similar to the spectra of its components and also exhibits a number of additional low-intensity lines. The experimental resul ts are interpreted using calculations of mixed crystals by the methods of a tom-atom potentials and of Dean. It is found that the experimental results better agree with calculations when the disordered distribution of-para-bro mochlorobenzene molecules over para-positions is taken into account (C) 200 0 MAIK "Nauka/Interperiodica".