alpha-Al2O3 crystals were treated in different atmospheres (reducing/oxidis
ing) at high temperature and their optical, positron-annihilation and therm
oluminescent (TL) properties were investigated. From optical absorption and
positron-annihilation spectra we concluded that aluminium-vacancies were c
reated while oxygen-vacancies were destroyed in oxidised samples indicating
a Schottky-type disorder. Structural changes were correlated with TL glow
curves and the origin of some TL peaks was explained.