A key property of the nitrides is the fact that they possess large spontane
ous and piezoelectric polarization fields that allow a significant tailorin
g of the carrier dynamics and optical properties of nitride devices. In thi
s paper, based on first-principles calculations of structural and electroni
c properties of bulk nitrides and their heterostructure. we investigate the
potential of this novel material class for modern device applications by p
erforming self-consistent Monte Carlo simulations. We demonstrate that the
internal electric fields have a significant and favorable influence an the
transistor characteristics.