Single crystals of the organic semiconductor perylene tetracarboxylic dianhydride studied by Raman spectroscopy

Citation
Da. Tenne et al., Single crystals of the organic semiconductor perylene tetracarboxylic dianhydride studied by Raman spectroscopy, PHYS REV B, 61(21), 2000, pp. 14564-14569
Citations number
16
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
PHYSICAL REVIEW B
ISSN journal
01631829 → ACNP
Volume
61
Issue
21
Year of publication
2000
Pages
14564 - 14569
Database
ISI
SICI code
0163-1829(20000601)61:21<14564:SCOTOS>2.0.ZU;2-7
Abstract
We present Raman studies of the vibrational properties of 3,4,9,10-perylene tetracarboxylic dianhydride (PTCDA) single crystals. Davydov splitting of internal molecular vibrations due to the interaction of two molecules in a unit cell was observed. Features of PTCDA crystal lattice vibrations in the low-frequency region of the Raman spectra are reported. PTCDA films deposi ted on passivated Si and GaAs surfaces also reveal the specific features of crystalline structure: Davydov splitting and appearance of phonon lines in Raman spectra.