Hyper-Raman spectroscopy is used to investigate low frequency vibrations of
various silica glasses. A strong boson peak is observed. The corresponding
modes are inactive in infrared and Raman spectra, and are nonacoustic in n
ature. The shape of this boson peak essentially matches the total density o
f vibrational states (DOS), with a constant coupling coefficient C. This an
d other indications suggest that these modes actually dominate the DOS of s
ilica.