Thermodynamic properties of gadolinium germanides at 298.15-2155 K

Authors
Gorbachuk, NP Bolgar, AS
Citation
Np. Gorbachuk et As. Bolgar, Thermodynamic properties of gadolinium germanides at 298.15-2155 K, POWD MET ME, 38(9-10), 1999, pp. 462-465
Citations number
8
Categorie Soggetti
Metallurgy
Journal title
POWDER METALLURGY AND METAL CERAMICS
ISSN journal
10681302 → ACNP
Volume
38
Issue
9-10
Year of publication
1999
Pages
462 - 465
Database
ISI
SICI code
1068-1302(199909/10)38:9-10<462:TPOGGA>2.0.ZU;2-1
Abstract
Enthalpies of the germanides Gd5Ge3 GdGe, and GdGe1.5 were measured in the range 298.15-2155 K for the first time by the method of mixing calorimetry. The temperatures, enthalpies, and entropies of melting of the compounds we re determined, and also those of the polymorphic transformations in GeGd1.5 . Equations for the temperature dependence of the basic thermodynamic funct ions over a wide temperature range were determined and recommended for prac tical use.