Effect of gamma-substitution on the thermoluminescence properties of terbium(III) acetylacetonate complexes with 1,10-phenanthroline

Authors
Karasev, VE Mirochnik, AG Polyakova, NV Lifar, LI
Citation
Ve. Karasev et al., Effect of gamma-substitution on the thermoluminescence properties of terbium(III) acetylacetonate complexes with 1,10-phenanthroline, RUSS CHEM B, 49(2), 2000, pp. 291-294
Citations number
10
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
2
Year of publication
2000
Pages
291 - 294
Database
ISI
SICI code
1066-5285(200002)49:2<291:EOGOTT>2.0.ZU;2-D
Abstract
The coordination compounds [Tb(NO3)(2)acac(phen)(2)]H2O (where acac is acet ylacetone or its derivatives substituted in the gamma-position) were synthe sized and studied by luminescence, IR, and UV spectroscopy. Thermoluminesce nce of the complexes containing acetylacetonate, 3-phenylthio-2,4-pentadion ate, and 3-(p-methoxyphenylthio)-2,4-pentadionate was found. The structural and electronic aspects of the crystal thermoluminescence were discussed.