Electrochemical synthesis and properties of sigma-fluoroacyl and sigma-perfluoroalkyl transition metal complexes

Authors
Denisovich, LI Peterleitner, MG Stepanov, AA Peregudova, SM
Citation
Li. Denisovich et al., Electrochemical synthesis and properties of sigma-fluoroacyl and sigma-perfluoroalkyl transition metal complexes, RUSS CHEM B, 49(2), 2000, pp. 375-377
Citations number
5
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
2
Year of publication
2000
Pages
375 - 377
Database
ISI
SICI code
1066-5285(200002)49:2<375:ESAPOS>2.0.ZU;2-D
Abstract
The electrochemical synthesis of sigma-fluoroacyl complexes [M]-sigma-CORf (M = C5H5(CO)(3)W or (CO)(5)Mn; R-f = CF3 or C4F9) was performed according to two procedures: (1) the preliminary electrochemical synthesis of [M](-) from [M](2) followed by reaction with a fluorine-containing compound and (2 ) the electrochemical synthesis of [M](-) in the presence of a fluorine-con taining compound. Trifluoroacetic anhydride was demonstrated to be the best acylating agent in these reactions. The electrochemical properties of the resulting complexes were studied.