Cj. Salomon et E. Breuer, Facile "one-pot" preparation of phosphonothiolformates. Useful reagents for the synthesis of carbamoylphosphonates, SYNLETT, (6), 2000, pp. 815-816
A versatile and mild "one-pot" reaction for the preparation of trialkyl pho
sphonothiolformates was accomplished by sequential reaction of phosgene sol
ution with alkanethiols, and subsequent Arbuzov reaction with trialkyl phos
phites.