Mt. Reetz et al., Entrapment of lipases in hydrophobic sol-gel-materials: Efficient heterogeneous biocatalysts in aqueous medium, SYNTHESIS-S, (6), 2000, pp. 781-783
The entrapment of certain lipases such as SP 525 (Candida antarctica B) or
SP 523 (Humicola lanuginosa) in hydrophobic sol-gel materials dc derived fr
om mixtures of RSi(OMe)(3) (R = alkyl) and Si(OMe)(4) or other alkyl-modifi
ed silane precursors results in heterogeneous biocatalysts which sri: remar
kably active in the hydrolysis of esters in aqueous medium. Relative activi
ties of 50-100% are typical.