Behaviour of terpene peroxides from abietic acid in the presence of heme and non-heme iron(II)

Authors
Muellner, U Huefner, A Haslinger, E
Citation
U. Muellner et al., Behaviour of terpene peroxides from abietic acid in the presence of heme and non-heme iron(II), TETRAHEDRON, 56(24), 2000, pp. 3893-3899
Citations number
39
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
56
Issue
24
Year of publication
2000
Pages
3893 - 3899
Database
ISI
SICI code
0040-4020(20000609)56:24<3893:BOTPFA>2.0.ZU;2-D
Abstract
In aqueous acetonitrile with FeCl2 or hemin/L-cysteine, a peroxide (4) obta ined from abietic acid by photosensitized air oxidation undergoes rearrange ment to give a diepoxide and two spiro compounds as major products. (C) 200 0 Elsevier Science Ltd. All rights reserved.