The lithium amide induced rearrangement of epoxysulfones derived from bicyclo[2.2.1]heptane system

Authors
Arjona, O Menchaca, R Plumet, J
Citation
O. Arjona et al., The lithium amide induced rearrangement of epoxysulfones derived from bicyclo[2.2.1]heptane system, TETRAHEDRON, 56(24), 2000, pp. 3901-3907
Citations number
50
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
56
Issue
24
Year of publication
2000
Pages
3901 - 3907
Database
ISI
SICI code
0040-4020(20000609)56:24<3901:TLAIRO>2.0.ZU;2-I
Abstract
Lithium amides induce rearrangement of the title compounds 1 to afford nort ricyclanones 4 via a ketocarbene intermediate. Compounds 4 undergo hydride transfer reduction and imino aldol condensation to afford the other observe d reaction products. (C) 2000 Elsevier Science Ltd. All rights reserved.