In Stranski-Krastanov mode, the transition from two-dimensional growth to t
hree-dimensional growth occurs at a certain thickness: a transition thickne
ss. In subsequent growth, misfit dislocations are incorporated at the inter
-face between the substrate and the epitaxially grown layer. This limited t
hickness for coherent growth is called: the critical thickness. An analytic
al equation for the transition thickness is derived by the thermodynamical
approach in which strain energy and surface energy are taken into account.
The three-dimensional island, often called a quantum dot, is stably formed,
when the strain energy of the two-dimensional layer exceeds the sum of the
relaxed strain energy and the excess surface energy of the three-dimension
al island. The equation is applied to obtain the transition thickness of In
As/GaAs, InP/ GaP, and Ge/Si which fit fairly well with the experimental re
sults. (C) 2000 Published by Elsevier Science S.A. All rights reserved.