The spontaneous organization of clusters of adsorbed metal atoms on surface
s is driven by the substrate temperature imposed during growth. The morphol
ogy and distribution of nanostructures can be controlled: from very small (
a few atoms) randomly distributed clusters to bigger (several 100 atoms) se
lf-organized clusters on a regular network, From a detailed variable temper
ature Scanning Tunneling Microscopy (STM) study, it is suggested that this
way of organizing matter at the nanoscale may be used to achieve new materi
al properties, In particular, on the example of Co on Au(111), it is shown
that the direction of the magnetization can be adjusted from in-plane to ou
t-of-plane, depending on the growth condition.