Surfactants are surface-active compounds capable of reducing surface and in
terfacial tension at the interfaces between liquids, solids and gases, ther
eby allowing them to mix or disperse readily as emulsions in water or other
liquids. The enormous market demand for surfactants is currently met by nu
merous synthetic, mainly petroleum-based, chemical surfactants. These compo
unds are usuary toxic to the environment and non-biodegradable. They may bi
o-accumulate and their production, processes and by-products can be environ
mentally hazardous. Tightening environmental regulations and increasing awa
reness for the need to protect the ecosystem have effectively resulted in a
n increasing interest in biosurfactants as possible alternatives to chemica
l surfactants. Biosurfactants are amphiphilic compounds of microbial origin
with considerable potential in commercial applications within various indu
stries. They have advantages over their chemical counterparts in biodegrada
bility and effectiveness at extreme temperature or pH and in having lower t
oxicity. Biosurfactants are beginning to acquire a status as potential perf
ormance-effective molecules in various fields. At present biosurfactants ar
e mainly used in studies on enhanced oil recovery and hydrocarbon bioremedi
ation. The solubilization and emulsification of toxic chemicals by biosurfa
ctants have also been reported. Biosurfactants also have potential applicat
ions in agriculture, cosmetics, pharmaceuticals, detergents, personal care
products, food processing, textile manufacturing, laundry supplies, metal t
reatment and processing, pulp and paper processing and paint industries. Th
eir uses and potential commercial applications in these fields are reviewed
.