We have investigated the structure and surface morphology of chemical-bath-
deposited (CBD) indium hydroxy sulphide thin Film using InCl3, thioacetamid
e (Tn) and acetic acid (AcOH). We have found that films are polycrystalline
and their structure depends on deposition conditions. When low TA and AcOH
concentrations are used, In5S4 is obtained; nevertheless, as these concent
rations are increased, films are composed by a mixture of the cubic alpha-
and beta-In2S3 phases. The film composition obtained by energy-dispersive X
-ray analysis (EDS) shows that samples are sulphur deficient (S/In ratios b
etween 0.5 and 1.2). The surface morphology of the films suggests two diffe
rent growth mechanisms. Which one takes place seems to be related to reacta
nt concentrations, especially to AcOH concentration. (C) 2000 Elsevier Scie
nce B.V. All rights reserved.