Cl. Zhan et Dy. Wang, Linearity relationship between solvatochromic shifts of stilbazolium-like dyes and modified reaction field function, CHIN J CHEM, 18(3), 2000, pp. 418-424
We analyzed statistically the linear correlation of the solvatochromic shif
ts of the stilbazolium-like dyes in the nonselected solvents with the react
ion field function, L(epsilon(r))-bL(n(2)), and the solvent polarity parame
ter, E-T(N), respectively, and observed that there were not perfectly linea
rity relationships between them, so we introduced E-T(N) into L(epsilon(r))
-bL(n(2)) to form a new reaction field function, L(epsilon(r))-bL(n(2)) + g
E-T(N), called as the modified reaction held function, which can be perfec
tly linearly correlated with the solvatochromic shifts of the stilbazolium-
like dyes in the nonselected solvents.