Soft magnetic nanocrystalline alloys have attracted great fundamental inter
est in recent years due to their two-phase structural and magnetic behaviou
r. We review first the reliability of the fitting procedures of spectra obt
ained by Fe-57 Mossbauer spectrometry which is a very efficient tool to inv
estigate such materials. Then, we report the common features which characte
rise the temperature dependence of Mossbauer spectra; the hyperfine field t
emperature dependence of both the crystalline grains and the intergranular
phase is discussed for different crystalline fractions in order to model th
e magnetic behaviour of the nanocrystalline alloys.