Self-association in gold chemistry: A tetragold(I) complex linked by both aurophilic and hydrogen bonding

Authors
Hunks, WJ Jennings, MC Puddephatt, RJ
Citation
Wj. Hunks et al., Self-association in gold chemistry: A tetragold(I) complex linked by both aurophilic and hydrogen bonding, INORG CHEM, 39(12), 2000, pp. 2699
Citations number
51
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
12
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000612)39:12<2699:SIGCAT>2.0.ZU;2-R
Abstract
Hydrolysis of the complex [1,3-C6H4(OPPh2AuSPh)(2)] gives the emissive, neu tral tetragold(I) complex [{Au-2(mu-SPh)(PPh2O)(PPh2OH)}(2)], which is asso ciated through pairs of gold ... gold interactions and P-O-H ... O-P hydrog en bonds.