A. Fajar et al., Electrooptic measurement in the vicinity of SmA-SmC alpha* phase transition of an antiferroelectric liquid crystal, JPN J A P 2, 39(2B), 2000, pp. L166-L168
EIectrooptic measurements have been performed around the SmA-SmCalpha+ phas
e transition point in an antiferroelectric liquid crystal 4-(1-methyl-hepty
loxycarbonyl)phenyl 4' -octyloxybiphenyl-4-carboxylate (MHPOBC). The first-
order electrooptic response was continuous with a small slope change at the
SmA to SmCalpha* transition point in the temperature dependence curve, whi
le the second-order electrooptic response exhibited an anomalous increase n
ear the transition point. We present a simple theory and demonstrate that t
his anomaly originates in the pretransitional fluctuations. The frequency d
ispersion of the electrooptic response is also presented.