Hydroxylation of alkanes catalysed by a chiral mu-oxo diferric complex: a metal-based mechanism

Authors
Mekmouche, Y Duboc-Toia, C Menage, S Lambeaux, C Fontecave, M
Citation
Y. Mekmouche et al., Hydroxylation of alkanes catalysed by a chiral mu-oxo diferric complex: a metal-based mechanism, J MOL CAT A, 156(1-2), 2000, pp. 85-89
Citations number
28
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN journal
13811169 → ACNP
Volume
156
Issue
1-2
Year of publication
2000
Pages
85 - 89
Database
ISI
SICI code
1381-1169(20000520)156:1-2<85:HOACBA>2.0.ZU;2-A
Abstract
The hydroxylation of alkanes by hydrogen peroxide catalysed by a chiral mu- oxo diferric complex has been demonstrated to be stereospecific and partial ly enantioselective indicating a metal-based mechanism. (C) 2000 Elsevier S cience B.V. All rights reserved.