Photolysis of 7,8-digermabicyclo[2.2.2]octadiene. The investigation of theelementary stages by means of H-1 CIDNP and laser pulse photolysis

Authors
Taraban, MB Volkova, OS Plyusnin, VF Ivanov, YV Leshina, TV Egorov, MP Nefedov, OM Kayamori, T Mochida, K
Citation
Mb. Taraban et al., Photolysis of 7,8-digermabicyclo[2.2.2]octadiene. The investigation of theelementary stages by means of H-1 CIDNP and laser pulse photolysis, J ORGMET CH, 601(2), 2000, pp. 324-329
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
601
Issue
2
Year of publication
2000
Pages
324 - 329
Database
ISI
SICI code
0022-328X(20000428)601:2<324:PO7TIO>2.0.ZU;2-N
Abstract
Photolysis of 7,8-digermabicyclo[2.2.2]octadiene (I) was studied by means o f H-1-CIDNP and laser pulse photolysis techniques. It was found that photod ecomposition of I occurs via germanium-centered 1,6-biradical species. 1,4- Diphenylnaghthalene and tetramethyldigermene are the primary products of th e photolytic reaction. (C) 2000 Elsevier Science S.A. All rights reserved.