Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH2CHMeCH2PPh2)(2) and (S)-Ph2PCH2CH(PPh2)CH2CH2PPh2)

Authors
Lee, HM Yang, CL Jia, GC
Citation
Hm. Lee et al., Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH2CHMeCH2PPh2)(2) and (S)-Ph2PCH2CH(PPh2)CH2CH2PPh2), J ORGMET CH, 601(2), 2000, pp. 330-334
Citations number
59
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
601
Issue
2
Year of publication
2000
Pages
330 - 334
Database
ISI
SICI code
0022-328X(20000428)601:2<330:PACHPO>2.0.ZU;2-G
Abstract
Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH2CHMeCH2PPh2)(2)) with NaBH4 prod uced Rh(BP4)(ttp*). The reaction of RuCl2(ttp*) with NaBH4 produced RuH(BH4 )(ttp*). The complexes RhCl(ttp*), RuCl2(ttp*), Rh(BH4)(ttp*), and RuH(BH4) (ttp*) were found to be catalytically active for the hydrogenation of alpha -acetamidocinnamic acid. (C) 2000 Elsevier Science S.A. All rights reserved .