On the in situ trimethylsilylation of zinc acetylides

Citation
U. Maeorg et al., On the in situ trimethylsilylation of zinc acetylides, J ORGMET CH, 601(2), 2000, pp. 341-342
Citations number
6
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
601
Issue
2
Year of publication
2000
Pages
341 - 342
Database
ISI
SICI code
0022-328X(20000428)601:2<341:OTISTO>2.0.ZU;2-O
Abstract
Reinvestigation of the recently published formation of silylated alkynes by reaction of 1-alkynes with zinc and trimethylchlorosilane in acetonitrile showed that appreciable amounts of 1-alkenes are formed as side products. ( C) 2000 Elsevier Science S.A. All rights reserved.