Addition of five-membered cyclic carbonate with amine and its application to polymer synthesis

Authors
Steblyanko, A Choi, WM Sanda, F Endo, T
Citation
A. Steblyanko et al., Addition of five-membered cyclic carbonate with amine and its application to polymer synthesis, J POL SC PC, 38(13), 2000, pp. 2375-2380
Citations number
9
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
ISSN journal
0887624X → ACNP
Volume
38
Issue
13
Year of publication
2000
Pages
2375 - 2380
Database
ISI
SICI code
0887-624X(20000701)38:13<2375:AOFCCW>2.0.ZU;2-N
Abstract
A bifunctional five-membered cyclic carbonate was synthesized from carbon d ioxide and diglycidyl terephthalate, and its polyaddition with alkyl diamin es were carried out in DMF at room temperature to obtain the corresponding poly(hydroxyurethane)s with M(n)s in the range of 6300-13200 in good yields . The structures of the obtained polymers were confirmed by IR and NMR spec troscopy and their glass-transition and decomposition temperatures were obs erved at 3-29 degrees C and 182-277 degrees C, respectively. (C) 2000 John Wiley & Sons, Inc.