A NEW AND EFFICIENT SYNTHESIS OF ROSEFURAN - A GENERAL-SYNTHESIS OF FURANS BY PALLADIUM-CATALYZED CYCLOISOMERIZATION OF (Z)-2-EN-4-YN-1-OLS

Citation
B. Gabriele et G. Salerno, A NEW AND EFFICIENT SYNTHESIS OF ROSEFURAN - A GENERAL-SYNTHESIS OF FURANS BY PALLADIUM-CATALYZED CYCLOISOMERIZATION OF (Z)-2-EN-4-YN-1-OLS, Chemical communications, (12), 1997, pp. 1083-1084
Citations number
28
Categorie Soggetti
Chemistry
Journal title
ISSN journal
13597345
Issue
12
Year of publication
1997
Pages
1083 - 1084
Database
ISI
SICI code
1359-7345(1997):12<1083:ANAESO>2.0.ZU;2-O
Abstract
(Z)-3,7-Dimethylocta-2,6-dien-4-yn-1-ol, readily available from (Z)-3- methylpent-2-en-4-yn-1-ol, undergoes cycloisomerization in the presenc e of catalytic amounts of K2PdI4 to give rosefuran in high yield.