ALKYL AND ALKYLIDENE DERIVATIVES OF TITANIUM SUPPORTED BY CARBAZOLE LIGATION

Authors
RILEY PN FANWICK PE ROTHWELL IP
Citation
Pn. Riley et al., ALKYL AND ALKYLIDENE DERIVATIVES OF TITANIUM SUPPORTED BY CARBAZOLE LIGATION, Chemical communications, (12), 1997, pp. 1109-1110
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
12
Year of publication
1997
Pages
1109 - 1110
Database
ISI
SICI code
1359-7345(1997):12<1109:AAADOT>2.0.ZU;2-Z
Abstract
The bis(benzyl) [(cb)(2)Ti(CH2Ph)(2)] 1 and alkylidene bridged dimer [ (cb)(2)Ti(mu-CHSiMe3)(2)Ti(cb)(2)] 3 are formed by adding carbazole (H cb) to the tetraalkyls [TiR4] (R = CH2Ph, CH2SiMe3); the reaction of 1 and 3 with 2,6-dimethylphenyl isocyanide leads to organometallic prod ucts containing new carbon-carbon bonds.