AXIAL LIGATION MODULATES THE ELECTRON-DISTRIBUTION IN HELICAL COBALT COMPLEXES DERIVED FROM OCTAETHYLBILINDIONE

Authors
ATTAR S OZAROWSKI A VANCALCAR PM WINKLER K BALCH AL
Citation
S. Attar et al., AXIAL LIGATION MODULATES THE ELECTRON-DISTRIBUTION IN HELICAL COBALT COMPLEXES DERIVED FROM OCTAETHYLBILINDIONE, Chemical communications, (12), 1997, pp. 1115-1116
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
12
Year of publication
1997
Pages
1115 - 1116
Database
ISI
SICI code
1359-7345(1997):12<1115:ALMTEI>2.0.ZU;2-N
Abstract
Addition of pyridine to the four-coordinate cobalt(II) complex, [Co-II (oebOx)]I-3, which shows an EPR spectrum with well resolved Co hyperfi ne coupling, converts the complex into one with Co-III/ligand radical structure and an EPR spectrum with g(z) = 1.98, and g(xy) = 2.02 and n o cobalt hyperfine coupling.