Baeyer-Villiger oxidation promoted by reaction of peracids with cyclic oxocarbenium ions generated in situ from internal hemiketals

Authors
Hunt, KW Grieco, PA
Citation
Kw. Hunt et Pa. Grieco, Baeyer-Villiger oxidation promoted by reaction of peracids with cyclic oxocarbenium ions generated in situ from internal hemiketals, ORG LETT, 2(12), 2000, pp. 1717-1719
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
12
Year of publication
2000
Pages
1717 - 1719
Database
ISI
SICI code
1523-7060(20000615)2:12<1717:BOPBRO>2.0.ZU;2-5
Abstract
[GRAPHICS] Reactive cyclic oxocarbenium ions, generated in situ from internal hemiketa ls, undergo Baeyer-Villiger oxidation upon exposure to m-chloroperbenzoic a cid leading, after hydrolysis of the resultant lactones, to acyclic fragmen ts for use in natural product synthesis.