Synthesis, structure, and fluxionality of (mu-diphenylsilylene)(fulvalene)tetracarbonyldirhenium-double Si-H activation to the first fulvalene silylene complex

Authors
Kayser, B Eichberg, MJ Vollhardt, KPC
Citation
B. Kayser et al., Synthesis, structure, and fluxionality of (mu-diphenylsilylene)(fulvalene)tetracarbonyldirhenium-double Si-H activation to the first fulvalene silylene complex, ORGANOMETAL, 19(12), 2000, pp. 2389-2392
Citations number
62
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
12
Year of publication
2000
Pages
2389 - 2392
Database
ISI
SICI code
0276-7333(20000612)19:12<2389:SSAFO(>2.0.ZU;2-G
Abstract
(Fulvalene)hexacarbonyldirhenium (1) furnishes the first silylene fulvalene dimetal complex 3 by double Si-H activation. The solid-state structure of t he molecule was determined by X-ray analysis and its solution dynamics by H -1 NMR spectroscopy.