G. Barbero et V. Poda-nita, Model for the planar-homeotropic anchoring transition induced by trans-cisisomerization, PHYS REV E, 61(6), 2000, pp. 6696-6698
We present a model to explain the planar-homeotropic anchoring transition o
f azobenzene induced by UV illumination via trans-cis isomerization. We con
sider bulk and surface as two different phases (separated by an infinitely
sharp interface) which are in equilibrium. We obtain a relation for the exp
osure time after which the transition takes place.