Cooperativity and spatial correlations near the glass transition: Computersimulation results for hard spheres and disks

Citation
B. Doliwa et A. Heuer, Cooperativity and spatial correlations near the glass transition: Computersimulation results for hard spheres and disks, PHYS REV E, 61(6), 2000, pp. 6898-6908
Citations number
19
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW E
ISSN journal
1063651X → ACNP
Volume
61
Issue
6
Year of publication
2000
Part
B
Pages
6898 - 6908
Database
ISI
SICI code
1063-651X(200006)61:6<6898:CASCNT>2.0.ZU;2-9
Abstract
We examine the dynamics of hard spheres and disks at high packing fractions in two and three dimensions, modeling the simplest systems exhibiting a gl ass transition. As it is well known, cooperativity and dynamic heterogeneit y arise as central features when approaching the glass transition from the liquid phase, so an understanding of their underlying physics is of great i nterest. Cooperativity implies a reduction of the effective degrees of free dom, and we demonstrate a simple way of quantification in terms of the stre ngth and the length scale of dynamic correlations among different particles . These correlations are obtained for different dynamical quantities X-i(t) that an constructed from single-particle displacements during some observa tion time t. Of particular interest is the dependence on t. Interestingly, for appropriately chosen X-i(t) we obtain finite cooperativity in the limit t-->infinity.