Influence of polydispersity on the viscoelastic properties of linear polydimethylsiloxanes and their binary blends

Linear polydimethylsiloxanes of relatively narrow molecular weight distribu tion (MWD) were synthesized by anionic polymerization and characterized by different techniques. Binary blends were also prepared with some of the syn thesized polymers. Linear viscoelastic parameters, such as storage (G') and loss (G ") moduli, were obtained at different temperatures as functions of frequency (omega). The time-temperature superposition principle was applie d in order to increase the frequency range measured. Zero-shear rate viscos ity (eta(0)), steady state recoverable compliance (J(e)(0)) and zero-shear rate first normal stress coefficient (psi(1,0)) were calculated from the da ta corresponding to the terminal relaxation zone. The molecular weight depe ndence of those parameters shows a good agreement with classical models and previously reported results, although J(e)(0) and psi(1,0) are strongly af fected by polydispersity. Different polydispersity factors were applied in order to fit the experimental values of the viscoelastic properties with th e theory. (C) 2000 Elsevier Science Ltd. All rights reserved.