We present a formalism for analyzing a full-sky temperature and polari
zation map of the cosmic microwave background. Temperature maps are an
alyzed by expanding over the set of spherical harmonics to give multip
ole moments of the two-point correlation function. Polarization, which
is described by a second-rank tensor, can be treated analogously by e
xpanding in the appropriate tensor spherical harmonics. We provide exp
ressions for the complete set of temperature and polarization multipol
e moments for scalar and tensor metric perturbations. Four sets of mul
tipole moments completely describe isotropic temperature and polarizat
ion correlations; for scalar metric perturbations one set is identical
ly zero, giving the possibility of a clean determination of the vector
and tensor contributions. The variance with which the multipole momen
ts can be measured in idealized experiments is evaluated, including th
e effects of detector noise, sky coverage, and beam width. Finally, we
construct coordinate-independent polarization two-point correlation f
unctions, express them in terms of the multipole moments, and derive s
mall-angle limits.