A dramatic modification of the ionization energy of Si donors has been obse
rved experimentally in a GaAs/AlGaAs double-well quantum-scale structure, c
aused by relocation of the electronic wave function from a delta-doped to a
n undoped quantum well in an external electric field. With the bias applied
to the structure changing by less than 1 V, the impurity ionization energy
falls from 15.5 meV down to zero. The observed anomalously high intensitie
s of the photoluminescence transitions involving the first excited electron
and heavy-hole subbands are explained by a distortion of the potential rel
ief of the structure by the built-in field.