N-H-Y coupling and localized vibration modes in MX compounds

Citation
Jh. Wei et al., N-H-Y coupling and localized vibration modes in MX compounds, SYNTH METAL, 113(1-2), 2000, pp. 193-197
Citations number
18
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
113
Issue
1-2
Year of publication
2000
Pages
193 - 197
Database
ISI
SICI code
0379-6779(20000615)113:1-2<193:NCALVM>2.0.ZU;2-J
Abstract
The effects of N-H-Y coupling on localized vibration modes around the excit ations in MX compounds are investigated. It is shown that the localized mod es in an isolated chain will be separated into two chains due to an N-H-Y c oupling. Some new modes of lattice vibration are found, which are achieved by the N-H-Y coupling. These results can qualitatively account for the freq uency shifts of some modes observed in the Raman and infrared absorption sp ectra. (C) 2000 Elsevier Science S.A. All rights reserved.