(o-Benzoquinone diimine-N,N ')dichlorobis(triphenylphosphine-P)-ruthenium(II) 1.33-methanol 0.33-dichloromethane solvate

Authors
Venegas-Yazigi, D Mirza, H Lever, ABP Lough, AJ Costamagna, J Vega, A Latorre, R
Citation
D. Venegas-yazigi et al., (o-Benzoquinone diimine-N,N ')dichlorobis(triphenylphosphine-P)-ruthenium(II) 1.33-methanol 0.33-dichloromethane solvate, ACT CRYST C, 56, 2000, pp. E245-E246
Citations number
24
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
6
Pages
E245 - E246
Database
ISI
SICI code
0108-2701(200006)56:<E245:(D'>2.0.ZU;2-I
Abstract
The Ru atom in the title compound, [RuCl2{P(C6H5)(3)}(2){C6H4(NH)(2)}]. 1.3 3CH(3)OH . 0.33CH(2)Cl(2), shows a six-coordinate octahedral geometry, with a trans arrangement of the triphenylphosphine groups. One and a half molec ules of complex, two molecules of methanol and a half molecule of dichlorom ethane form the asymmetric unit, with crystallographic twofold rotation sym metry for the complex molecule in a special position.