(Acetonitrile-N)(o-benzoquinone diimine-N,N ')chloro-trans-bis(triphenylphosphine-P)ruthenium(II) hexafluorophosphate 0.25-hydrate

Authors
Venegas-Yazigi, D Mirza, H Lever, ABP Lough, AJ Costamagna, J Latorre, R
Citation
D. Venegas-yazigi et al., (Acetonitrile-N)(o-benzoquinone diimine-N,N ')chloro-trans-bis(triphenylphosphine-P)ruthenium(II) hexafluorophosphate 0.25-hydrate, ACT CRYST C, 56, 2000, pp. E247-E248
Citations number
6
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
6
Pages
E247 - E248
Database
ISI
SICI code
0108-2701(200006)56:<E247:(D'>2.0.ZU;2-C
Abstract
The Ru atom in the title compound, [RuCl(CH3CN){P(C6 H-5)(3)}(2){C6H4(NH)(2 )}]PF6. 0.25H(2)O, has a six-coordinate octahedral geometry, with a trans a rrangement of the triphenylphosphine groups. The asymmetric unit contains t wo complex molecules and a partially occupied water site. Principal dimensi ons include Ru-N 1.958 (4)-2.044 (5), Ru-P 2.3897 (16)-2.4092 (15), and Ru- Cl 2.4280 (15) and 2.4295 (16) Angstrom.