A 4-COMPONENT PHASE-DIAGRAM

Citation
Se. Friberg et Brc. Langlois, A 4-COMPONENT PHASE-DIAGRAM, Langmuir, 10(9), 1994, pp. 2939-2944
Citations number
34
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
07437463
Volume
10
Issue
9
Year of publication
1994
Pages
2939 - 2944
Database
ISI
SICI code
0743-7463(1994)10:9<2939:A4P>2.0.ZU;2-D
Abstract
A complete phase diagram was determined for the system water, decane, isostearic acid, and triethanolamine using optical microscopy and low- angle X-ray diffraction. The system contained two isotropic liquids in the form of an isostearic acid/decane solution with dissolved trietha nolamine as well as a water/triethanolamine solution with dissolved is ostearic acid and decane. Two lyotropic liquid crystals were found, on e of lamellar structure and one consisting of a hexagonal array of clo se-packed cylinders. Of the two-phase spaces connecting the two liquid s with the lamellar liquid crystal one was initiated toward the aqueou s solution/decane line, while the other on emanated from the decane/is ostearic acid/triethanolamine plane.