Two photochemical pathways in competition: matrix isolation, time-resolvedand NMR studies of cis-[Ru(PMe3)(4)(H)(2)]

Authors
Montiel-Palma, V Perutz, RN George, MW Jina, OS Sabo-Etienne, S
Citation
V. Montiel-palma et al., Two photochemical pathways in competition: matrix isolation, time-resolvedand NMR studies of cis-[Ru(PMe3)(4)(H)(2)], CHEM COMMUN, (13), 2000, pp. 1175-1176
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
13
Year of publication
2000
Pages
1175 - 1176
Database
ISI
SICI code
1359-7345(2000):13<1175:TPPICM>2.0.ZU;2-A
Abstract
cis-[Ru(PMe3)(4)(H)(2)] (1) reacts by two distinct photochemical pathways r esulting in the formation of [Ru(PMe3)(4)] and [Ru(PMe3)(3)(H)(2)]; derivat ives of these intermediates are generated in the presence of CO and Ph2SiH2 .