Xl. Hou et al., Novel N,S- and N,Se-planar chiral [2,2]paracyclophane ligands: synthesis and application in Pd-catalyzed allylic alkylation, CHEM COMMUN, (13), 2000, pp. 1195-1196
Novel N,S- and N,Se-ligands with planar chirality derived from [2.2]paracyc
lophane have been synthesized and applied in palladium-catalyzed allylic al
kylation reaction, in which ligands 5 and 9 with the two substituents at be
nzylic and benzene ring positions give the highest ee values.