Synthesis and structure of bis(2,4-dimethylpentadienyl)gadolinium chloride

Citation
Jh. Wang et al., Synthesis and structure of bis(2,4-dimethylpentadienyl)gadolinium chloride, CHEM J CH U, 21(6), 2000, pp. 829-831
Citations number
5
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
21
Issue
6
Year of publication
2000
Pages
829 - 831
Database
ISI
SICI code
0251-0790(200006)21:6<829:SASOBC>2.0.ZU;2-F
Abstract
A new complex {[2, 4-(CH3)(2)C5H5](2)GdCl)(2) was obtained by the reaction of [2,4-(CH3)(2)C5H5](3)Gd with GdCl3 in toluene at refluxing temperature. The compound {[2,4-(CH3)(2)C5H5](2)GdCl)(2) crystallizes in the monoclinic system, space group P2(1)/n with a = 0.891 41 (18) nm, b = 1. 448 6(3) nm, c = 1. 159 25 (15) nm, beta = 92. 996(18)degrees, V = 1. 494 9(4) nm(3), Z = 3.