Synthesis of novel group 4 metallocene-containing silsesquioxanes with a vinyl group

Authors
Wada, K Bundo, M Nakabayashi, D Itayama, N Kondo, T Mitsudoh, T
Citation
K. Wada et al., Synthesis of novel group 4 metallocene-containing silsesquioxanes with a vinyl group, CHEM LETT, (6), 2000, pp. 628-629
Citations number
19
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
6
Year of publication
2000
Pages
628 - 629
Database
ISI
SICI code
0366-7022(20000605):6<628:SONG4M>2.0.ZU;2-Y
Abstract
Novel zirconocene or hafnocene-containing silsesquioxanes with a vinyl grou p Cp2M{[(vinyl)Me2Si](c-C5H9)(7)Si7O12} (Cp = cyclopentadienyl, M = Zr, Hf) were synthesized, as well as a derivative with a trimethylsilyl group Cp2Z r[(Me3Si)(c-C5H9)(7)Si7O12]. A derivative containing a dimethylethoxysilyl group was also synthesized.