Osmium isotopes in hydrothermal fluids from the Juan de Fuca Ridge

We present Os data for axial high-temperature and off-axial low-temperature hydrothermal solutions from the Juan de Fuca Ridge. The high-temperature, H2S-bearing axial fluids have unradiogenic Os isotopes pointing to a nearly complete domination of osmium isotopes from the basalts during hydrotherma l circulation. The ridge axis fluids typically do not show large enrichment in osmium concentration over seawater although one high-temperature fluid has an Os concentration enhanced by a factor of 4 above seawater. It appear s that the Os concentration of high-temperature hydrothermal fluids is typi cally buffered at roughly the seawater concentration. We suggest that subse afloor precipitation of pyrite from the high-temperature hydrothermal fluid s controls the osmium transportation. The axial hydrothermal activity does not supply significant amounts of unradiogenic osmium to the deep oceans. I n contrast, a low-temperature off-axis fluid is enriched in non-radiogenic osmium over seawater by a factor of 9, showing much less precipitation of o smium at low temperature. Because a large fraction of the cooling of oceani c lithosphere occurs on ridge flanks, Os from low-temperature, ridge-flank hydrothermal circulation may be a significant contributor to the balance of Os in the oceans. A detailed balance between Os contributions from dissolu tion of cosmic dust and hydrothermal fluids is still not possible. The low- temperature hydrothermal sample gives Os-187/Os-188 = 0.110 +/- 0.001. This extremely unradiogenic osmium can only come from a source that underwent d epletion of Re over 2.6 Ga ago. Assuming no contamination during sample col lection, this result suggests that the convecting upper mantle contains anc ient depleted material that imparted unradiogenic osmium to intruding basal tic melts. (C) 2000 Elsevier Science B.V, All rights reserved.