The effect of atomic order on environmental embrittlement of an Fe3Al-
based alloy was studied. The ordered B2 and DO3 structures are much mo
re susceptible to the test environments (air versus vacuum) than the d
isordered structure. The embrittlement index, I, of B-2, DO3 and disor
dered structures is 62.1%, 62.5% and 21.7%, respectively. The disorder
ed Fe-Al alloy showed the transgranular cleavage fracture mode wheneve
r tested in vacuum or in air. A mixed intergranular/transgranular clea
vage fracture mode was observed for both ordered alloys tested in vacu
um. When tested in air, the B2 alloy continued to fracture via the mix
ed mode, while the DO3 alloy exhibited mainly transgranular cleavage f
racture.