Chemiion concentration measurements in jet engine exhaust at the ground: Implications for ion chemistry and aerosol formation in the wake of a jet aircraft

Total positive chemiion concentrations n in jet engine exhaust at the groun d were measured using an electrostatic probe. Data were obtained for two di fferent engines (RR M45H and JT9D-7) for one power setting (half thrust), t wo fuel sulfur contents (2 and 66 ppmm); and four distances d (1.39, 2.19, 4.19, and 18.6 m) behind the engines. The corresponding plume ages t(p) ran ged from about 12 to 170 ms. As t(p) increases n decreases steeply from 1.6 x10(8) cm(-3) at t(p) = 12 ms to 3x10(6) cm(-3) at t(p) = 170 ms. We conclu de that this decrease mostly reflects ion removal by ion-ion recombination with a mean rate coefficient of about 7.5x10(-7) cm(3)/s. Our experimental findings have interesting implications for the chemical evolution and poten tial roles of chemiions in jet engine exhaust plumes. These implications ar e briefly addressed.